AS CHEMISTRY

ALKANES AND FUELS

MULTIPLE CHOICE TEST

 

1.  The general formula for alkanes is...

CnH2n-2
CnH2n
CnH2n+2

CnH3n

 


2.  The empirical formula of cyclohexane is ...

CnH2n+2
CH2
C3H7

C6H12

 


3.   Which of the following straight chain alkanes has the highest boiling point?

C2H6
C3H8
C4H10

C5H12

 


4.  Which of the following alkanes has the lowest boiling point?

CH3CH2CH2CH2CH3
CH3CH(CH3)CH2CH3
CH3CH2CH2CH2CH2CH3

CH3C(CH3)2CH3

 


5.  What is the name of the compound with the structural formula, CH3CH(CH3)CH(CH3)CH2CH3?

heptane
2,3-dimethylpentane
2,3-methylpentane
3,4-dimethylpentane

 


6.  The number of structural isomers with the molecular formula C5H12 is...

2
3
4

5

 


7.  The alkane which requires 5 moles of oxygen per mole for complete combustion is...


C2H6
C3H8
C4H10

C5H12

 


8.  Which one of the following emissions from car exhausts is not classed as a pollutant?


carbon dioxide
carbon monoxide
nitrogen oxides

unburnt hydrocarbons

 


9.  Which one of the following is not a fossil fuel?


coal
gas
oil

wood

 

 


10.  Which one of the following is a non-renewable energy source?


radioactivity
solar power
 wind power

wave power

 


11.  Which one of the following statements about free radicals is not true?


they are produced during the chlorination of methane in the presence of UV light
they contain a lone pair of electrons
they are formed during homolysis of covalent bonds

they are formed during the thermal cracking of hydrocarbons

 


12.  The order of stages in the reaction between chlorine and methane in UV light is...


propagation, initiation, termination
termination, propagation, initiation
initiation, propagation, termination

initiation, termination, propagation

 


13.  The first step of the reaction between chlorine and methane in UV light involves...


breaking a C-C bond
breaking a C-H bond
breaking a Cl-Cl bond

the formation of Cl¯ ions

 


14.  Which reaction is not a propagation step in the reaction between methane and excess chlorine?


CH3•  +   Cl2     ——>   CH3Cl   +  Cl•
CH3•  +   Cl•     ——>   CH3Cl
Cl•   +   CH4     ——>   CH3•   +   HCl

CH3Cl   +  Cl•   ——>   CH2Cl•  +  HCl

 


15.  Which organic product is most likely to be present following the reaction between excess
        chlorine and methane in the presence of UV light?


CH2Cl2
CHCl3
CCl4

HCl

 


16.  Which of the following statements about fractional distillation of crude oil is not true?


the more volatile fractions condense further up the tower
compounds with a small number of carbon atoms are less volatile
compounds with a large number of carbon atoms condense at higher temperatures

compounds with a large number of carbon atoms are likely to be viscous

 


17.  Which one of the following fractions is the most volatile?

bitumen
gasoline
kerosene
naphtha

 


18.  Which process in the oil and petroleum industry is used to obtain cycloalkanes?

fractional distillation
cracking
isomerisation

reforming

 


19.  Which one of the following statements about thermal cracking is not true?

it involves a free radical mechanism
it takes place at high temperatures and pressures
it involves heterolytic fission

ethene and hydrogen are useful products

 


20.  Which one of the following statements about catalytic cracking is not true?


it involves breaking down more useful compounds into smaller and more useful ones
catalytic cracking involves a free radical mechanism
catalytic cracking involves heterolytic fission

catalytic cracking involves ions



      

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