AS CHEMISTRY
ALKANES AND FUELS
MULTIPLE CHOICE TEST
1. The general formula for alkanes is... CnH2n-2 CnH2n CnH2n+2
CnH3n
2. The empirical formula of cyclohexane is ... CnH2n+2 CH2 C3H7
C6H12
3. Which of the following straight chain alkanes has the highest boiling point? C2H6 C3H8 C4H10
C5H12
4. Which of the following alkanes has the lowest boiling point? CH3CH2CH2CH2CH3 CH3CH(CH3)CH2CH3 CH3CH2CH2CH2CH2CH3
CH3C(CH3)2CH3
5. What is the name of the compound with the structural formula, CH3CH(CH3)CH(CH3)CH2CH3? heptane 2,3-dimethylpentane 2,3-methylpentane 3,4-dimethylpentane
6. The number of structural isomers with the molecular formula C5H12 is... 2 3 4
5
7. The alkane which requires 5 moles of oxygen per mole for complete combustion is...
C2H6 C3H8 C4H10
8. Which one of the following emissions from car exhausts is not classed as a pollutant?
carbon dioxide carbon monoxide nitrogen oxides
unburnt hydrocarbons
9. Which one of the following is not a fossil fuel?
coal gas oil
wood
10. Which one of the following is a non-renewable energy source?
radioactivity solar power wind power
wave power
11. Which one of the following statements about free radicals is not true?
they are produced during the chlorination of methane in the presence of UV light they contain a lone pair of electrons they are formed during homolysis of covalent bonds
they are formed during the thermal cracking of hydrocarbons
12. The order of stages in the reaction between chlorine and methane in UV light is...
propagation, initiation, termination termination, propagation, initiation initiation, propagation, termination
initiation, termination, propagation
13. The first step of the reaction between chlorine and methane in UV light involves...
breaking a C-C bond breaking a C-H bond breaking a Cl-Cl bond
the formation of Cl¯ ions
14. Which reaction is not a propagation step in the reaction between methane and excess chlorine?
CH3• + Cl2 ——> CH3Cl + Cl• CH3• + Cl• ——> CH3Cl Cl• + CH4 ——> CH3• + HCl
CH3Cl + Cl• ——> CH2Cl• + HCl
15. Which organic product is most likely to be present following the reaction between excess chlorine and methane in the presence of UV light?
CH2Cl2 CHCl3 CCl4
HCl
16. Which of the following statements about fractional distillation of crude oil is not true?
the more volatile fractions condense further up the tower compounds with a small number of carbon atoms are less volatile compounds with a large number of carbon atoms condense at higher temperatures
compounds with a large number of carbon atoms are likely to be viscous
17. Which one of the following fractions is the most volatile? bitumen gasoline kerosene naphtha
18. Which process in the oil and petroleum industry is used to obtain cycloalkanes? fractional distillation cracking isomerisation
reforming
19. Which one of the following statements about thermal cracking is not true? it involves a free radical mechanism it takes place at high temperatures and pressures it involves heterolytic fission
ethene and hydrogen are useful products
20. Which one of the following statements about catalytic cracking is not true?
it involves breaking down more useful compounds into smaller and more useful ones catalytic cracking involves a free radical mechanism catalytic cracking involves heterolytic fission
catalytic cracking involves ions
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