AS CHEMISTRY

ALCOHOLS

MULTIPLE CHOICE TEST

 


1.  What is the name of the compound with the structural formula, CH3CH(CH3)CHOHCH3?

pentanol
2-methylbutanol
2-methylbutan-3-ol

3-methylbutan-2-ol

2.  The empirical formula of butan-2-ol is...


CHO
CH2O
C2H5O

C4H10O

 

3.   Which of the following compounds has the highest boiling point?


C3H6
C3H8
C2H5OH

CH3OCH3

 

 

4.  What is the name of the compound with the structural formula, (CH3)3COH?


butanol  
2-methylpropan-2-ol
1,1,1-trimethylmethanol

2-methylpropan-1-ol

 

 

5.  The number of structural isomers of alcohols with the molecular formula C4H10O is...


2

3
4

5

 

 

 

6.  The number of primary (1°) alcohols with molecular formula C4H10O is...


0
1
2

3

 

 

7.  The C-O-H bond angle in ethanol is approximately...


90°
104.5°
107°

109.5°

 

 

8.  Which one of the following methods cannot be used to make ethanol?


fermentation of glucose
oxidation of ethanal
hydration of ethene using steam

the reaction between chloroethane and aqueous sodium hydroxide

 

 

 

9.  How many moles of oxygen are required exactly for the complete combustion of one mole of C3H7OH?


3
4

5

 

 

 

10.  Which one of the following cannot be made directly from propan-1-ol?


propanone
propene
 1-bromopropane

propyl ethanoate

 

 

 

 

11.  Which one of the following statements about the oxidation of alcohols is true?


tertiary alcohols are easily oxidised
secondary alcohols are easily oxidised to aldehydes
primary alcohols are easily oxidised to aldehydes

when acidified potassium dichromate is used to oxidise alcohols, it turns from green to orange

 

    

 

12.  Which one of the following is formed when butanal is reduced?


but-1-ene
butanoic acid
butan-2-ol

butan-1-ol

 

 

 

13.  Which one of these is true of the laboratory conversion of ethanol into ethanal?


it involves reduction
the mixture is refluxed
distillation apparatus is used

ethanol has a lower boiling point than ethanal

 

   

 

14.  Which of the following cannot be used to differentiate between butanal and butanone


ammoniacal silver nitrate solution
Fehling's solution
Tollen's reagent

bromine water

 

 

 

15.  The reaction between ethanol and ethanoic acid is an example of...


esterification
free radical substitution
addition

elimination

 

 

 

16.  Which of the following statements about the reaction between methanol and ethanoic acid is not true?


it is an example of equilibrium
it uses concentrated sulphuric acid as a catalyst
ethyl methanoate is formed

methyl ethanoate is formed

 

 

 

17.  Which pair of compounds can be used to make propyl methanoate?


CH3OH and CH3COOH
C3H7OH and CH3COOH
C3H7OH and HCOOH

CH3OH and C2H5COOH

 

.

 

18.  Which one of the following is true about esters?


They are formed from aldehydes reacting with alcohols.
They form intermolecular hydrogen bonds between themselves.
They can be hydrolysed to give alcohols and carboxylic acids.

They have no commercial use.

 

 

 

19.  Which of the following methods could not be used to differentiate ethanal from propanal?


molecular mass determination
empirical formula determination
Tollen’s reagent

boiling point

 

 

20.  Which one of the following statements about infrared spectra is not true?


alcohols show an absorption at about 3500cm-1
aldehydes and ketones show an absorption at around 1650cm-1
carboxylic acids show absorptions at around 1650cm-1 and at about 3000cm-1

esters show an absorption at about 3500cm-1


      

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